Product ID:BUTYL OLEATE DLC-A
MSDS Date:03/11/1994
FSC:8030
NIIN:00N057615
MSDS Number: CCWMP

NATROCHEM INC

SAVANNAH, GA 31498-4201
US

Emergency Phone: 912-236-4464

Info Phone: 912-236-4464

Preparer: JAMES L. FRYE JR.

Cage: 9C469

NATROCHEM INC

1205 SAVANNAH, GA 31498-4201 US

Telephone: 912-236-4464

Cage: 9C469

9-OCTADECANOIC ACID, BUTYL ESTER (Z)-; (BUTYL OLEATE).

CAS: 142-77-8

RTECS: RG3711000

OSHA PEL N/K

ACGIH TLV: N/K

SILICA GEL; (SILICON DIOXIDE)

CAS: 112945-52-5

RTECS: VV7310000

Fraction By Weight: 26-30%

OSHA PEL 6 MG/M3

ACGIH TLV: 10 MG/M3

VIA INHAL TO LEVELS OF PRECIPITATED SILICA DUST OF

RTECS: 9999999ZZ

ALTHOUGH PRECIPITATED SILICA WAS TEMPORARILY

RTECS: 9999999ZZ

SOON AFTER DUST EXPOS ENDED. RSLTS OF ALL STUDIES

RTECS: 9999999ZZ

PULMONARY ACTIVITY FOR SYNTHETIC PRECIPITATED SILICA.

RTECS: 9999999ZZ

NORMAL PROCESSING. ALL POSS HLTH EFTS ARE NOT KNOWN &

RTECS: 9999999ZZ

SHOULD ALWAYS BE PROVIDED TO DRAW DUST, FUMES & VAPS

RTECS: 9999999ZZ

BE ADEQUATE TO MAINTAIN AMBIENT WORKPLACE ATMOSPHERES

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:MILDLY IRRIT. EXCESSIVE
CONT W/POWDER CAN CAUSE DRYING OF MUC MEMBS DUE TO ABSORPTION OF
MOISTURE & OILS. SKIN:ABSORPTION & MILDLY IRRIT. INHAL:NUISANCE
DUST. EXCESSIVE CONT W/POWDER CAN CA USE DRYING OF MUC MEMBS OF
NOSE & THROAT DUE TO ABSORPTION OF MOISTURE & OILS. THIS MATL CAN
ALSO CAUSE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:NASAL IRRIT & NOSEBLEEDS. INGEST:NOT
SIGNIFICANTLY TOX. CHRONIC:AN EPIDEMIOLOGICAL STUDY WAS CONDUCTED
WHICH INCLUDED 165 PRECIPITATED SILICA WORKERS WHO HAD BEEN EXPOS
FOR AVG OF 18 YRS. NO ADVERSE EFTS WERE NOTED IN COMPLETE MEDEXAM
(INCL CHEST ROENTGENOGRAMS) OF THESE WORKERS. PULM FUNC DECREMENTS
(SUPDAT)
Medical Cond Aggravated by Exposure:PERSONS W/BREATHING PROBLEMS OR
LUNG DISEASE SHOULD NOT WORK IN DUSTY AREAS UNLESS MD APPROVES &
CERTIFIES THEIR FITNESS TO WEAR NIOSH APPROVED RESPIRATORY
PROTECTION.

First Aid:EYES:IMMEDIATELY RINSE W/CLEAN WATER FOR AT LEAST 15 MINUTES.
RETRACT EYELIDS OFTEN. IF IRRITATION PERSISTS, SEEK MEDICAL
ATTENTION. SKIN:IMMEDIATELY REMOVE CONTAMINATED CLOTHING. WASH SKIN
THOROUGHLY W/MILD SOAP & WATER. FLUSH W/LUKEWARM WATER FOR 15
MINUTES. SEEK MEDICAL ATTENTION IF ILL EFFECT OR IRRITATION
DEVELOPS. INHAL:REMOVE VICTIM TO FRESH AIR. INGEST:CONSULT MD.

Flash Point Method:COC
Flash Point:390F,199C
Extinguishing Media:WATER FOG, FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.

Spill Release Procedures:MINIMIZE SPILL AREA. VACUUM SPILL MATERIAL &
PLACE IN CLOSED PLASTIC BAGS FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:HANDLING CAN CREATE EXPLOSIVE DUST
CLOUDS. ELIMINATE IGNITION SOURCES, USE EXPLOSIVE PROOF EQUIPMENT.
AVOID DUST ACCUMULATIONS.
Other Precautions:CONVEYING & PROCESSING EQUIPMENT SHOULD BE
SPARK-PROOF, WELL BONDED & GROUNDED.

Respiratory Protection:USE A NIOSH APPROVED RESPIRATOR SUCH AS 3M 9900
OR EQUIVALENT FOR PROTECTION AGAINST PNEUMOCONIOSIS PRODUCING
DUSTS.
Ventilation:PROVIDE EXPLO PROOF VENT AS REQD TO CONTROL AIRBORNE DUST
LEVELS. SUM TOTAL OF ALL INGS MAY EMIT VAPS DURING (ING 7)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMOKING/USING TOILET FACILITIES. LAUNDER CONTAM CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
CNDTNS(STAB):SUGGESTED HOWEVER SINCE MATL HAS DEMONSTRATED INSTABILITY
W/OUT PRESENCE OF ANTIOXIDANT. MATLS TO AVOID:ADDITIVES MAY ALTER
TOXICOLOGICAL PROPERTIES. EFTS OF OVEREXP:WERE CORRELATED ONLY
W/SMOKING & AGE BUT NOT W/DEGREE OR DURATION OF DUST EXPOS. LAB
STUDIES HAVE ALSO BEEN CONDUCTED IN SM ANIMALS (ING 3)

Boiling Pt:B.P. Text:>266F,>130C
Vapor Pres:NEGLIGIBLE
Spec Gravity:1.033
Solubility in Water:NEGLIGIBLE
Appearance and Odor:OFF-WHITE, FREE FLOWING POWDER W/MILD FATTY ACID
ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID ALTERATION OF PROD PROPERTIES BEFORE REUSE. CALCINING, WHICH MAY
RSLT IN CRYSTALLINE FORM OR MIXING W/ (SUPP DATA)
Stability Condition to Avoid:AVOID HIGH TEMPS (>800C) TREATMENT. THIS
PROD CNTNS ANTIOXIDANT WHICH MAKES IT THERMALLY STABLE. CAUTION IS
(SUPP DATA)
Hazardous Decomposition Products:OXIDES OF CARBON.

Waste Disposal Methods:WASTE DISPOSAL METHOD I/A/W LOCAL, STATE &
FEDERAL REGULATIONS.

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